Hi,
As you can see, the Toolset many-to-many relationship works only for two post types, it does not work for wordpress users.
But I think there is a workaround for your case, for example:
1) you can setup a custom post type "Invitation", with two custom fields:
a) Numeric field (inviting user ID)
b) checkbox field(Accept)
2) Create a view to list all wordpress users, when click the link, pass the user's ID as an URL parameter "inviting-user-id" to the target page
3) In the target page, create a CRED form with field (inviting user ID) for creating "Invitation" post, the value of field "inviting user ID" is preset by URL parameter "inviting-user-id":
https://toolset.com/documentation/user-guides/cred-shortcodes/#cred_field
value: Preset value
4) Create another page "My invitations", in this page, create a view list "Invitation" posts, filter by the field (inviting user ID) equal to current user's ID:
https://toolset.com/documentation/user-guides/filtering-views-by-custom-fields/#source-for-compare-value
Shortcode attribute: The value for the filter comes from an attribute in the View shortcode
https://toolset.com/documentation/user-guides/views-shortcodes/#wpv-current-user
This shortcode outputs the information about the current, logged-in user.
And display a CRED form edit link of below CRED form:
https://toolset.com/documentation/user-guides/displaying-cred-editing-forms/
5) Create a CRED form for editing "Invitation" post, with checkbox field(Accept), user can accept the invitation.
6) Create a page "Accepted invitations", in this page, create a view, list "Invitation" posts, filter by post author is current user, and field(Accept) is enabled, so users will be able to see all "Accepted invitations"
https://toolset.com/documentation/user-guides/filtering-views-query-by-author/
For your reference.