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Toolset doesn't have a time field, it has a date field where the date can also include the time, which is probably not what you need.
In the absence of a time field, you could add a free form text field, but then you can't control very easily for people entering the time in different formats, or you could create select dropdown fields.
If the acceptable times are limited, e.g. only every half hour during an 8 hour working day, then you could probably use a single select field, adding the options 09:00, 09:30, 10:00 etc., or you could add a separate field for the hour and another for the minutes (maybe you only need 00, 15, 30, 45, etc.).